The bookies also quote him at 8-1 to beat Holland next week and help secure the job on a full-time basis. Both sides are 6-4 with Ladbrokes and the draw is 11-5.
Sunderland striker Fraizer Campbell's surprise addition to the squad see his odds of making the finals plane slashed to 6-1 and he's 3-1 to make a scoring debut, as well as being 4-1 to start the game.
Steven Gerrard is odds-on (4-6) favourite to wear the armband for the match while Scott Parker is next at 13-8 having been all the rage in the earlier captaincy betting heats.
Alex Donohue of Ladbrokes said: “It will be interesting to see how the odds change when we know more about the Dutch side. As it stands we think it's a highly winnable game for Pearce and if they do the business his odds will be cut to get the job on a full-time basis.”
William Hill are offering 25-1 the two meet in the Final of Euro 12 and 11-8 a caretaker boss will still be managing the side when that tournament gets underway.
Who Will Start England’s Opening Euro Game v France (William Hill odds): Scott Parker: 4/11 Yes, 2/1 No, Theo Walcott: 4/7 Yes, 5/4 No. John Terry: 5/6 Yes, 5/6 No. Daniel Sturridge: 11/10 Yes, 4/6 No. Rio Ferdinand: 11/10 Yes, 4/6 No. Micah Richards: 6/4 Yes, 1/2 No. Frank Lampard: 7/4 Yes, 2/5 No. Chris Smalling: 7/4 Yes, 2/5 No. Leighton Baines: 2/1 Yes, 4/11 No. Stewart Downing: 2/1 Yes, 4/11 No Adam Johnson: 11/4 Yes, 1/4 No. Tom Cleverley: 7/2 Yes 1/6 No. Danny Welbeck: 4/1 Yes, 1/7 No. Kyle Walker: 4/1 Yes, 1/7 No. Fraizer Campbell: 6/1 Yes, 1/12 No. Robert Green: 7/1 Yes, 1/16 No. Scott Carson: 10/1 Yes, 1/33 No.